Overview of the latest issue of Angewandte Chemie
Angewandte Chemie 48/2022: Expanding the Repertoire
Direct Reaction of Nitroarenes and Thiols Gives Sulfonamides
Photoexcitation of nitroarenes leads to oxygen transfer from a nitro group to a thiol group
Conformers Undergo Different Reactions Controlled by Quantum Tunneling
Unprecedented reaction gives distinct rearrangement products that cannot be explained by classical reactivity models
Visible-Light-Driven Synthesis of Bicyclo[2.1.1]hexanes
Intramolecular crossed [2 + 2] photocycloaddition leads to useful building blocks
Primeval Reaction Pathways
Some reactions in the reverse Krebs cycle can be run under meteorite catalysis
Cycloparaphenylenes with a Twist
Alkene insertion into cycloparaphenylenes gives circular molecules with Möbius topology
Quasi-[7]Circulenes Prepared from Aza[5]helicenes
Electrophilic borylation followed by formation of an N→B bond
In-situ Phosgene Synthesis from Chloroform
Photochemical oxidation of chloroform in a continuous flow reactor for on-demand phosgenation
Dimethyl Ether Activates Metal–Organic Frameworks
Gentle method for MOF activation removes guest solvent molecules and prevents structural collapse
TiCl4-Catalyzed Reduction of Carboxylic Acids to Alcohols
Safe reduction protocol for a broad range of acids using NH3BH3