Photoexcitation of nitroarenes leads to oxygen transfer from a nitro group to a thiol group
Direct Reaction of Nitroarenes and Thiols Gives Sulfonamides
Conformers Undergo Different Reactions Controlled by Quantum Tunneling
Unprecedented reaction gives distinct rearrangement products that cannot be explained by classical reactivity models
Visible-Light-Driven Synthesis of Bicyclo[2.1.1]hexanes
Intramolecular crossed [2 + 2] photocycloaddition leads to useful building blocks
Primeval Reaction Pathways
Some reactions in the reverse Krebs cycle can be run under meteorite catalysis
Cycloparaphenylenes with a Twist
Alkene insertion into cycloparaphenylenes gives circular molecules with Möbius topology
Quasi-[7]Circulenes Prepared from Aza[5]helicenes
Electrophilic borylation followed by formation of an N→B bond
In-situ Phosgene Synthesis from Chloroform
Photochemical oxidation of chloroform in a continuous flow reactor for on-demand phosgenation
Dimethyl Ether Activates Metal–Organic Frameworks
Gentle method for MOF activation removes guest solvent molecules and prevents structural collapse
TiCl4-Catalyzed Reduction of Carboxylic Acids to Alcohols
Safe reduction protocol for a broad range of acids using NH3BH3
Styrene Derivatives Synthesized from Allyl Silanes
Allyl silanes isomerized to alkenyl silanes, followed by a Hiyama coupling