New Route to Chiral Amides

New Route to Chiral Amides

One-pot method generates chiral amides from secondary alcohols with retention of stereochemistry and provides evidence for non-planar carbocations

P4 Activation with Silylenes

P4 Activation with Silylenes

Activation of white phosphorus with silylenes gives two unusual Si–P compounds that could be precursors for semiconducting materials

New Method for Adding Alkyl Groups

New Method for Adding Alkyl Groups

New method for adding methyl groups to aldehydes gives the highest enantioselectivities and yields reported and can be used for longer alkyl chains

Light Vortex

Light Vortex

Simply stirring a gelled solution of dye can result in circularly polarized luminescence

Molecular Remodeling

Molecular Remodeling

A diverse library of compounds for pharmaceutical screening can be created starting with a single reactive natural product, according to US chemists