Reactions of primary sulfonamides with alkenes under photoredox conditions

Cyclic Amines Synthesized Using a Radical-Polar Crossover Cycloaddition

Practical α-Heteroarylation of Nitriles
Copper-mediated radical-based reaction using azobis(alkylcarbonitriles) as precursors

Angewandte Chemie 10/2024: Leverage
Overview of the latest issue of Angewandte Chemie

Total Synthesis of (–)-Lemnalemnane A
Asymmetric path to rare rearranged sesquiterpenoid in 13 steps

α-Arylation of Cyclic 1,3-Dicarbonyls
Convenient strategy via the generation of cyclic iodonium ylides followed by rhodium-catalyzed coupling with arylboronic reagents

Transition-Metal-Free Alkylation of N-Heterocycles with Nitriles
Direct synthesis of phosphonium salts from benzothiazoles and pyridines allows a two-step protocol for C−H functionalization

Selective Alkylation of 4-Aminoindoles
Carbene-catalyzed regio- and enantioselective reaction with α-bromoenals

Quaternary Carbon Centers Built Using an Iron-Catalyzed Coupling Reaction
Coupling of tertiary alkyl halides with secondary alkyl zinc reagents gives products with high steric hindrance

Buckybowl Conformation Controlled by Crystallization Solvent
Monofluorosumanene forms crystals with entirely different dielectric responses depending on the crystallization conditions

Angewandte Chemie 9/2024: Exploration
Overview of the latest issue of Angewandte Chemie