Convenient strategy via the generation of cyclic iodonium ylides followed by rhodium-catalyzed coupling with arylboronic reagents

α-Arylation of Cyclic 1,3-Dicarbonyls

Transition-Metal-Free Alkylation of N-Heterocycles with Nitriles
Direct synthesis of phosphonium salts from benzothiazoles and pyridines allows a two-step protocol for C−H functionalization

Selective Alkylation of 4-Aminoindoles
Carbene-catalyzed regio- and enantioselective reaction with α-bromoenals

Quaternary Carbon Centers Built Using an Iron-Catalyzed Coupling Reaction
Coupling of tertiary alkyl halides with secondary alkyl zinc reagents gives products with high steric hindrance

Buckybowl Conformation Controlled by Crystallization Solvent
Monofluorosumanene forms crystals with entirely different dielectric responses depending on the crystallization conditions

Angewandte Chemie 9/2024: Exploration
Overview of the latest issue of Angewandte Chemie

Roeland Nolte (1944 – 2024)
Dutch chemist known for his wide range of work in supramolecular chemistry passed away

Nonaromatic Through-Bond Conjugation Affects Photoluminescence
New concept helps to explain the photoluminescence of nontraditional luminogens

Chiral Double π-Helical Nanoribbons
Creating a platform to understand how chirality spreads and dissymmetry amplifies

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