Amides reacted with benzyl chloroformate (Cbz-Cl) to give N-Cbz amides for transamidations

Transamidation Reactions at Room Temperature

Asymmetric Substitution of Methyl Azaarenes
Iridium-catalyzed asymmetric allylic alkylation reaction

Pushing the Length Limit of Dihydrodiboraacenes
Boron‐embedded heptacene and nonacene synthesized

Carboxylic Acids Used Directly as Acyl Radical Precursors
Boronic-acid-mediated photocatalysis enables intramolecular hydroacylation of olefins

An Extremely Bulky Cyclopentadienyl Ligand
Complete series of alkali metal salts of a penta-terphenyl cyclopentadienyl ligand prepared

Cyanogramides B and C Synthesized
Biosynthetic precursors of a spiro indole alkaloid from marine-derived bacteria

Stable Aromatic Trications
Tricarboxybenzenes were (tri)protonated to give surprisingly stable species

Engineered Enzymes Used to Synthesize Biaryls
Biocatalytic cross-couplings with cytochrome P450 enzymes

Priestley Medal 2022 for Peter B. Dervan
Highest honor of the American Chemical Society (ACS) presented to researcher working at the interface of chemistry and biology

First Total Synthesis of (−)-3-Oxoisotaxodione
Chiral bicyclic hydrazide used as an organocatalyst for key synthetic step