Reactions using β-diketiminate metal complexes with H2 or CH4 as the only byproducts

Catalytic C–H Zincation and C–H Alumination of Heteroarenes

An Enantioselective Biocatalytic C–H Fluorination
Directed evolution used to create a fluorinating enzyme

Perchlorate Used for Iron-Catalyzed C–H Oxygenations
Oxygenation of anthracene and cyclic alkyl aromatics in high yields

Efficient Access to S-Adenosylmethionine Analogs
Enzymatic alkylation of S-adenosyl-L-homocysteine using iodoalkanes

Carbene Insertion into the γ-C–H Bonds of Aliphatic Amines
Regioselective transformation uses a palladium catalyst and a picolinamide directing group

Behind the Science: Self-Consistent Convolutional Density Functional Approximations
A proof-of-concept functional, PBEq, that can distinguish between electronic environments within a system by using different approximations at different points in space

Organocatalyst Streamlines Hybrid Anionic Block Copolymerization
Cooperative effect of an organobase and triethylborane used for efficient polymerization

Decarboxylative Amination of Substituted Malonic Acid Half Oxyesters
Organocatalyzed reaction with dialkyl azodicarboxylates gives α-aminoester derivatives

Angewandte Chemie 13/2024: Innovation and Team Spirit
Overview of the latest issue of Angewandte Chemie

Angewandte Chemie 12/2024: Cooperation
Overview of the latest issue of Angewandte Chemie