MOFs containing Co(III) halide sites as heterogeneous catalysts for the introduction of chlorine or fluorine into (hetero)aryl bromides

Metal–Organic Frameworks as Catalysts for Halogen Exchange

Clara Immerwahr Award 2024
Meera Mehta, University of Oxford, UK, honored for outstanding achievements in catalysis research

Cobalt-Catalyzed Propargylic Dehydrogenation Gives Z-Enynes
Simple catalytic system compatible with a variety of functional groups

Catalytic C–H Zincation and C–H Alumination of Heteroarenes
Reactions using β-diketiminate metal complexes with H2 or CH4 as the only byproducts

An Enantioselective Biocatalytic C–H Fluorination
Directed evolution used to create a fluorinating enzyme

Perchlorate Used for Iron-Catalyzed C–H Oxygenations
Oxygenation of anthracene and cyclic alkyl aromatics in high yields

Efficient Access to S-Adenosylmethionine Analogs
Enzymatic alkylation of S-adenosyl-L-homocysteine using iodoalkanes

Carbene Insertion into the γ-C–H Bonds of Aliphatic Amines
Regioselective transformation uses a palladium catalyst and a picolinamide directing group

Behind the Science: Self-Consistent Convolutional Density Functional Approximations
A proof-of-concept functional, PBEq, that can distinguish between electronic environments within a system by using different approximations at different points in space

Organocatalyst Streamlines Hybrid Anionic Block Copolymerization
Cooperative effect of an organobase and triethylborane used for efficient polymerization