Presence of a stable Fe(IV)-O₂•⁻ complex inside a nanocage in water for the first time at room temperature reported

Rare Stable Fe(IV)-Superoxo Intermediate at Room Temperature

Diboratriazole Radical Anion Isolated
One-electron reduction gives π-delocalized radical with an inorganic ring skeleton

A Synthetic Mimic for Cosmic Dust
Phenanthrene/pyrene hybrid microparticles can stand in for cosmic dust rich in polycyclic aromatic hydrocarbons (PAHs)

Three-Component Reaction Gives Substituted Pyridines
Deoxygenative transformation involving alcohols, styrenes, and cyanopyridines

Electrochemical Reduction of Disulfides
Vitamin B12-catalyzed transformation of a wide range of substrates, from small molecules to proteins

Can Large Language Models Predict Inorganic Syntheses?
Fine-tuned large language models (LLMs) found to perform similar to or better than specialized machine learning models for certain chemical tasks

Hydride-Free Copper Nanocluster for Catalysis
Atomically precise, luminescent copper nanocluster can promote photoinduced C–C coupling reactions

How Do Capping Agents Affect the Redox Potential of Nanoparticles?
Substantial potential differences observed between identical gold nanoparticles with 2- or 4-mercaptobenzoic acid ligands

Enantioselective Hydroxylation of Tertiary Propargylic C–H bonds
Manganese-catalyzed enantio-differentiating hydroxylation in acyclic systems

Vanadium-Dependent Chloroperoxidase for Regioselective Halogenation
Lavanducyanin halogenase (LvcH) discovered and used in chemoenzymatic synthesis