Can manganese photoredox catalysts enable efficient radical cross-coupling reactions?
Advanced Manganese Photocatalysts with Boron-NHC Ligands
Rare Stable Fe(IV)-Superoxo Intermediate at Room Temperature
Presence of a stable Fe(IV)-O₂•⁻ complex inside a nanocage in water for the first time at room temperature reported
Diboratriazole Radical Anion Isolated
One-electron reduction gives π-delocalized radical with an inorganic ring skeleton
A Synthetic Mimic for Cosmic Dust
Phenanthrene/pyrene hybrid microparticles can stand in for cosmic dust rich in polycyclic aromatic hydrocarbons (PAHs)
Three-Component Reaction Gives Substituted Pyridines
Deoxygenative transformation involving alcohols, styrenes, and cyanopyridines
Electrochemical Reduction of Disulfides
Vitamin B12-catalyzed transformation of a wide range of substrates, from small molecules to proteins
Can Large Language Models Predict Inorganic Syntheses?
Fine-tuned large language models (LLMs) found to perform similar to or better than specialized machine learning models for certain chemical tasks
Hydride-Free Copper Nanocluster for Catalysis
Atomically precise, luminescent copper nanocluster can promote photoinduced C–C coupling reactions
How Do Capping Agents Affect the Redox Potential of Nanoparticles?
Substantial potential differences observed between identical gold nanoparticles with 2- or 4-mercaptobenzoic acid ligands
Enantioselective Hydroxylation of Tertiary Propargylic C–H bonds
Manganese-catalyzed enantio-differentiating hydroxylation in acyclic systems