Partial nitro reduction of methyl 2-nitrobenzoates followed by base-mediated cyclization, alkylation, and reduction gives useful bicyclic compounds
Practical Path to Dihydrobenzisoxazoles
Dinitrogen Turned into a Photoswitch
First lanthanide N2 photoswitch shows isomerization between side-on and end-on coordination
Twisting Alkyne Cycloparaphenylenes into a Molecular Pinwheel
Strain-promoted alkyne cyclotrimerization gives curved carbon nanostructures
Cubane Derivatives with Unusually Short Carbon–Halogen Bonds
Hexafluorodihalocubanes feature some exceptionally short bonds, including the shortest C(sp3)–I bond found so far
A Path to Substituted Bicyclo[2.1.1]hexanones
Two-step transformation combines a transannular pinacol coupling reaction with a pinacol rearrangement
Fast-Cycling Electrochemistry in Microclouds
Self-electrification by fast phase switching affects redox reactions
Enantioselective Decarboxylative Difluoromethylation
Nickel-catalyzed decarboxylative transformation of alkyl carboxylic acids with good functional group tolerance
Peroxide-Based Coating Approach Gives Nanoshells with Alkali Metals
Difficult-to-achieve uniform coating prepared using hydrogen peroxide as a precipitant
Polarity of Over 550 Radicals Calculated
Electrophilicity/nucleophilicity of common open-shell synthetic intermediates calculated and experimentally validated
Frustrated Lewis Pair Anchored on Copper Nanoclusters for Catalysis
Immobilized catalysts for hydrogenation reactions provide high activity and regioselectivity