Hexafluorodihalocubanes feature some exceptionally short bonds, including the shortest C(sp3)–I bond found so far
Cubane Derivatives with Unusually Short Carbon–Halogen Bonds
A Path to Substituted Bicyclo[2.1.1]hexanones
Two-step transformation combines a transannular pinacol coupling reaction with a pinacol rearrangement
Fast-Cycling Electrochemistry in Microclouds
Self-electrification by fast phase switching affects redox reactions
Enantioselective Decarboxylative Difluoromethylation
Nickel-catalyzed decarboxylative transformation of alkyl carboxylic acids with good functional group tolerance
Peroxide-Based Coating Approach Gives Nanoshells with Alkali Metals
Difficult-to-achieve uniform coating prepared using hydrogen peroxide as a precipitant
Polarity of Over 550 Radicals Calculated
Electrophilicity/nucleophilicity of common open-shell synthetic intermediates calculated and experimentally validated
Frustrated Lewis Pair Anchored on Copper Nanoclusters for Catalysis
Immobilized catalysts for hydrogenation reactions provide high activity and regioselectivity
Enantioselective Alkylation of Primary Phosphines
Nickel-catalyzed asymmetric transformation using alkyl halides gives P-stereogenic secondary phosphine-boranes with high enantioselectivity
Twisting Planar Aromatic Compounds into a Figure Eight
Oxidative cleavage of an internal double bond of a polycyclic aromatic hydrocarbon (PAH) gives a figure-eight-shaped macrocycle
Gold(I) Catalysis Provides Access to Alkynyl C-Glycosides
Silyl-assisted, gold(I)-catalyzed transformation gives useful precursors for complex glycosides