Ring-opening and ring-closing approach gives pyridinium salts that can be converted to N-(hetero)arylpiperidine derivatives
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General Path to N-Arylpiperidines
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Cyclization of 5-Iodo-4-Pentenenitriles Gives Cyclopentenones
Ligand-free Pd(0)-catalyzed cyclization followed by imine hydrolysis
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4-Iodine N-Methylpyridinium for Solid-Phase Peptide Synthesis
Bench-stable and cost-effective coupling reagent
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Molecular Tweezers Made from Carbaporphyrin Linked to Nanographenes
Hybrid systems act as receptors for relatively large substrates
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Triplet Vinylarsinidene Synthesized
Higher congener of vinylnitrene prepared by low-temperature photolysis or high-vacuum flash pyrolysis
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General Path to 3-Methylindoles
Oxazoline palladacycle with NHC ligand catalyzes cyclization reaction of ortho-dihaloarenes and N-allylamines
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Defluoroalkylation of gem-Difluoroalkenes
α-Fluoroalkenyl alcohols prepared via C–F/C–H coupling
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Electrochemical Ring-Opening of Cyclopropylamides to Give 1,3-Oxazines
Method avoids the need for external oxidants and has a broad substrate scope
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Nanofibrous Membranes for Oil-Water Separation
Polymer composite membrane containing metal–organic framework (MOF) particles and carbon nanotubes (CNTs)
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1,1- and 1,3-Aminoboration of Unactivated Alkenes
Nickel-catalyzed reaction provides versatile difunctionalized products