Introduction of thermolytically labile pendant groups allows for catalyst-free reversion to monomers

Depolymerizable Methacrylate Polymers

Selective Alkylation of 4-Aminoindoles
Carbene-catalyzed regio- and enantioselective reaction with α-bromoenals

Quaternary Carbon Centers Built Using an Iron-Catalyzed Coupling Reaction
Coupling of tertiary alkyl halides with secondary alkyl zinc reagents gives products with high steric hindrance

Buckybowl Conformation Controlled by Crystallization Solvent
Monofluorosumanene forms crystals with entirely different dielectric responses depending on the crystallization conditions

Chiral Double π-Helical Nanoribbons
Creating a platform to understand how chirality spreads and dissymmetry amplifies

First Complex With a Plutonium Carbon Double Bond
Preparation of a diphosphoniomethanide-Pu complex along with two diphosphonioalkylidene-Pu complexes

Palladium-Catalyzed Aminoalkynylation Gives Chiral Isoindolinones
Efficient coupling of O-phenyl hydroxamic ethers with terminal alkynes

Efficient Radioiodination of Arenes
Clean radioiodination of aryl boronic acids at room temperature using low loadings of a copper precatalyst

First Chalcogen Bonds Centered at Water Oxygen Atoms
Highly polarized water molecules trapped between two lithium ions show unprecedented interaction

Cube-Shaped, Water-Stable Boronate Ester Cages
Steric shielding provides unprecedented stability