Steric shielding provides unprecedented stability

Unique nucleophilic reactivity allows for additions across the C−C triple bond of arynes

Two carbene centers on a single ring can bind two metals with short intermetallic distances

Previously unknown Sc(II) scandocene complexes obtained via reduction of bis(cyclopentadienyl) scandium iodides

Reductive approach involves the generation of N-radical cations

Method based on ANRORC (addition of nucleophile, ring opening, ring closing) reactions allows the labeling of a wide range of aromatic nitrogen-containing heterocycles

Path to dihydropyridine cis-diols and epoxides

N-difluoromethyl carbamoyl fluorides used as robust building blocks for amides, (thio)carbamates, ureas, and formamides

Radical-radical coupling of heteroaryl phosphonium salts with N-heteroarenes

Hexacyclic alkaloid with a sterically crowded tetrasubstituted benzene ring