Carbene-catalyzed regio- and enantioselective reaction with α-bromoenals

Coupling of tertiary alkyl halides with secondary alkyl zinc reagents gives products with high steric hindrance

Monofluorosumanene forms crystals with entirely different dielectric responses depending on the crystallization conditions

Creating a platform to understand how chirality spreads and dissymmetry amplifies

Preparation of a diphosphoniomethanide-Pu complex along with two diphosphonioalkylidene-Pu complexes

Efficient coupling of O-phenyl hydroxamic ethers with terminal alkynes

Clean radioiodination of aryl boronic acids at room temperature using low loadings of a copper precatalyst

Highly polarized water molecules trapped between two lithium ions show unprecedented interaction

Steric shielding provides unprecedented stability

Unique nucleophilic reactivity allows for additions across the C−C triple bond of arynes