Fast-Cycling Electrochemistry in Microclouds
Self-electrification by fast phase switching affects redox reactions
Enantioselective Decarboxylative Difluoromethylation
Nickel-catalyzed decarboxylative transformation of alkyl carboxylic acids with good functional group tolerance
Peroxide-Based Coating Approach Gives Nanoshells with Alkali Metals
Difficult-to-achieve uniform coating prepared using hydrogen peroxide as a precipitant
Polarity of Over 550 Radicals Calculated
Electrophilicity/nucleophilicity of common open-shell synthetic intermediates calculated and experimentally validated
Frustrated Lewis Pair Anchored on Copper Nanoclusters for Catalysis
Immobilized catalysts for hydrogenation reactions provide high activity and regioselectivity
Enantioselective Alkylation of Primary Phosphines
Nickel-catalyzed asymmetric transformation using alkyl halides gives P-stereogenic secondary phosphine-boranes with high enantioselectivity
Twisting Planar Aromatic Compounds into a Figure Eight
Oxidative cleavage of an internal double bond of a polycyclic aromatic hydrocarbon (PAH) gives a figure-eight-shaped macrocycle
Gold(I) Catalysis Provides Access to Alkynyl C-Glycosides
Silyl-assisted, gold(I)-catalyzed transformation gives useful precursors for complex glycosides
New Strategy to Access Ketyl Radical Anions
Coupling of aldehydes and alkenes via α-hydroxy sulfinate and ketyl radical anion intermediates
2-Aminopyridines Made from Bench-Stable Reagents
2-Halopyridinium ketene hemiaminals allow for nucleophilic aromatic substitutions with amines
Organocatalyst for Electrochemical Hydrogen Evolution
Metal-free, N-heterocyclic phosphine (NHP)-type organocatalyst provides high activity
Metal-Free Synthesis of (Per)Fluoroalkyl-Functionalized Nitro-Indoles
Base-catalyzed intramolecular cyclization of N-acyl amides provides access to indole derivatives
Bismuth Catalyst Can Degrade the Stable SF6
Pincer bismuthinidene complexes allow reactions with inert greenhouse gas and the related PhSF5
α-Spiropyrrolidones Made from Aminobinaphthalinols
Amino-functionalized derivatives of the well-known BINOL ligands oxidized to induce a skeletal rearrangement
Bacteria Produce Mevalonate from CO2
"Plasmid addiction system" ensures successful biosynthesis
New Gel for Solar-Driven Atmospheric Water Harvesting
Highly hygroscopic, LiCl-modified composite material shows high water adsorption performance and stability
Enantioselective Total Synthesis of Cyathin B2
Platinum-catalyzed diboration/double-allylboration cascade used to prepare a cyathane diterpenoid
Phase-Transfer Catalysis for the Alkylation of Pyrazolones
Enantioselective alkylation of 4-substituted pyrazolones using inexpensive halohydrocarbons
Direct α-Carbonyl Carbene Insertion into B–H Bonds of Amine-Boranes
A photoinduced, selective, and direct B–H insertion reaction using amine-boranes under metal-free and photocatalyst-free conditions