Overview of the latest issue of Angewandte Chemie

Angewandte Chemie 48/2024: Guidance

Making Cyclobutenes from Cyclopropyl Carbenes
Transition-metal-free, fluoro-promoted thermal rearrangement

Frustrated Lewis Pairs with Unsupported Group 14–Aluminium Bonds
New class of frustrated Lewis pairs (FLPs) also features the first structurally authenticated Al–Pb bond

New Option for the Late-Stage Dimethylation of Arenes
Site-selective thianthrenation combined with with a Catellani reaction provides access to 3,5-dimethylated arenes

Tumor Cells Suffer Copper Withdrawal
Nanofibers made of copper-binding peptides disrupt copper homeostasis in cancer cells

Crown Ether-Based Calcium Detection in Partially Aqueous Solutions
Simon Wheeler, UK, discusses his new fluorescent sensor for Ca²⁺

Carboranyl Diphosphine Activates Ammonia
Metal-free, room-temperature N–H bond activation

Electrolysis and Organic Synthesis Decoupled to Achieve Rare Selectivity
Ex-situ electro-oxidation pairs hydrogen generation with aldehyde production

Molecular “Frame” Stabilizes T-Shaped Rhodium Complexes
14-Electron Rh(I) complexes with PNP pincer ligands can undergo oxidative additions with unactivated C–H bonds

Template Controls Carbon Nanotube Diameter
Hydrocarbon belts used as organic templates for the synthesis of single-walled carbon nanotubes