In this issue, S. Rohn et al. review the reactivity of glucosinolates and their breakdown products in foods. How do they affect the quality of food with regard to nutritional value, flavor, and beneficial health effects? In a Minireview, R. J. M. Nolte et al. discuss the advances in processive catalysis that have been made in emulating it through supramolecular chemistry. The Highlights deal with the trifluoromethanide anion (N. Santschi and R. Gilmour) and transition-metal-based ¹⁸F fluorination (S. H. Liang and N. Vasdev).

In the Communications section, I. Ivanović-Burmazović et al. describe the effect of confined space around a heme iron center (see picture). J. Ye et al. demonstrate photothermal conversion of CO₂ into methane over Group VIII nanocatalysts as an option for solar fuel production. R. Giri et al. succeeded in the copper-catalyzed coupling of triaryl- and trialkylindium reagents with aryl iodides and bromides, and N. W. Mitzel et al. present the solid-state structure of pentafluoroethyllithium, a Li/F carbenoid.

• Angewandte Chemie 43/2014: Long-Term Stability,
  Angew. Chem. Int. Ed. 2014, 43.