Al–Mg–Al system shows both radical chemistry and nucleophilic behavior at aluminium

Bis(Aluminyl)Magnesium Compound with Dual Reactivity

Uranyl Captured in a Heterobimetallic Crown Ether Complex
Tailored macrocyclic ligand forms an isolable complex with UO22+

Carbene Insertion into the γ-C–H Bonds of Aliphatic Amines
Regioselective transformation uses a palladium catalyst and a picolinamide directing group

Salts of Protonated Sulfur Dioxide Synthesized
Elusive hemi- and monoprotonated SO2 cations isolated as Sb2F11− salts

Organocatalyst Streamlines Hybrid Anionic Block Copolymerization
Cooperative effect of an organobase and triethylborane used for efficient polymerization

Does the Ligand Connectivity of MOFs Affect Their Mechanical Stability?
High-pressure behavior of metal–organic frameworks (MOFs) with different linkers compared

The First Crystalline Compound with a –C≡C–COO– Anion
Double deprotonation of propiolic acid gives elusive, Y-shaped anion

Azoxy-Triazenes Used for the Aziridination of Alkenes
Readily available species serving as nitrogen atom sources in a photoinduced transformation

Decarboxylative Amination of Substituted Malonic Acid Half Oxyesters
Organocatalyzed reaction with dialkyl azodicarboxylates gives α-aminoester derivatives

Creating Patterns in Living Bacterial Biofilms
Photodynamic biopatterning technique provides high spatial resolution