Cláudio M. Nunes and Peter R. Schreiner discuss controlling quantum mechanical tunneling (QMT) reactivity by modifying electronic substituents and why QMT should be included in general chemistry curricula
Authors discuss their recent research article

Tuning Quantum Mechanical Tunneling Reactivity with Electron-Donating Substituents

Chiral Pd Lantern Cage Synthesized with Peptide
The design principles of metallo-organic ligands were applied to polyproline peptides, leading to the synthesis of a stable, stereoselective Pd lantern cage in water

Bioinspired CO2 Capture: Exploring Dipeptides for Efficient Carbon Sequestration
The use of dipetides for CO2 capture and a new computational workflow and statistical analysis of effective binding sites

Phosphine-Stabilized P4C4 Cage Compound
First synthetic access to a phosphine-stabilized P4C4 cage, expanding the exploration of P,C phases in contrast to the well-studied P,N phases

Magnetized Droplet Chains in Liquid Crystals
Varun Chandrasekhar, Jian Ren Lu, Ingo Dierking, University of Manchester, explore how ferrofluids, when dispersed in liquid crystals, form unique droplet chains with magnetic functionality

Crown Ether-Based Calcium Detection in Partially Aqueous Solutions
Simon Wheeler, UK, discusses his new fluorescent sensor for Ca²⁺

Triel Bonds: New Pathway to Pentacoordinate Carbon
Study provides the first evidence of a pentacoordinate carbon in a stable complex, offering insights relevant to chemical bonding and biological methyl transfer processes

A New Chapter in Magnetism: The Role of Symmetry in Luminescent Yb3+ Complexes
Although the prolate single molecule magnets known from the textbook have large ground state splittings, this does not lead to strong magnetism

Sustainable Aqueous Calcium-Ion Battery
Highly stable aqueous battery based on saturated CaCl2 with excellent fast charging capabilities developed

Understanding Polymerization in Extraterrestrial Ices
How can complex organic molecules like paraldehyde be synthesized in extraterrestrial ices?