An attempt to prepare sterically protected tungsten corroles led to the first free-base corrole radical. In their Communication in Angewandte Chemie, Martin Bröring and colleagues, Technical University Braunschweig, Germany, report an air-stable and easy-to-handle open-shell 17π-porphyrinoid 1 with a SOMO (singly occupied molecular orbital) that resembles the symmetry of a Rorschach or inkblot image (see above).
The researchers see their corrole radical, of course. We collected some of our own ideas below. What do you see in the picture? |
Trees |
Plane |
Teddy |
Drone |
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- The Corrole Radical,
Peter Schweyen, Kai Brandhorst, Richard Wicht, Benedikt Wolfram, Martin Bröring,
Angew. Chem. Int. Ed. 2015.
DOI: 10.1002/anie.201503624